Photochemistry of bichromophoric chain molecules containing electron donor and acceptor moieties. Dependence of reaction pathways on the chain length and mechanism of photoredox reaction of N-|ω-(p-nitrophenoxy)alkyl|anilines

✍ Scribed by Ryoichi Nakagaki; Mitsuo Hiramatsu; Kiyoshi Mutai; Saburo Nagakura

• Publisher: Elsevier Science
• Year: 1985
• Tongue: English
• Weight: 409 KB
• Volume: 121
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(85)85522-6

✦ Synopsis

lrrsr,rure f<>r hfolccular Sclencr hf, odqt 0huzaX1 -#4J Jopun Surwhmg of pholochemlcsl renc~lon pathnays NBS round [or 3 senes or blchromophorlc sprees D-(CH,),,-A conr~srmg or electron donor and nccrplor molehe~ by changmg the number ol mcthylcne groups hnh~ng IWO chromophora Long-chom molecules (n > 8) shoa ;1 pholoredox reacmm *hrIe short-ch.un compounds (n < 6) exhlblr Ihe photo-Smllec rcarrangemen~ when D = amlino and A = p-nrlrophenoq group ' PresLnl address Hamamalru Pholomcs K K Ichmo-cho Ham.lmauu 435. Japan ' Prcscm address College or AVIS snd %ences. The Under-s11y or Tokyo Komaba. Meguro Tokyo 153. Japnn