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Photochemistry of .beta.,.gamma.-unsaturated ketones. 10,11-Dimethyltricyclo[4.3.2.0]undec-10-en-2-one

✍ Scribed by Peet, Norton P.; Cargill, Robert L.; Crawford, James W.

Book ID: 126477177
Publisher: American Chemical Society
Year: 1973
Tongue: English
Weight: 270 KB
Volume: 38
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo00946a035

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## Abstract On ^1^n,π\*‐excitation, the title compound **2** undergoes a photoinduced intramolecular [4 + 2]‐cycloaddition affording the tetracyclic enol ether **3** as the only product in 79% yield. The assigned structure of **3** was confirmed by its conversion to the __p__‐nitrobenzoate **6** wh