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Photochemistry of a Retinal Protonated Schiff-Base Analogue Mimicking the Opsin Shift of Bacteriorhodopsin

โœ Scribed by Bismuth, Oshrat; Friedman, Noga; Sheves, Mordechai; Ruhman, Sanford

Book ID
125810239
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
394 KB
Volume
111
Category
Article
ISSN
0022-3654

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A blue shift of protonated retinal schif
A blue shift of protonated retinal schiff base. A model study for bacteriorhodopsin
โœ Mordechai Sheves; Timor Baasov ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 191 KB

A blue shift was observed in the absorption maxima of protonated retinal Schiff base. The shift is due to electrostatic interaction of a non-conjugated positive charge, located in the vicinity of the ionone moiety, with the polyene chromophore.