Photochemistry of a matrix-isolated geminal diazide. Dimethylgermylene
โ Scribed by Barrau, Jacques.; Bean, Dennis L.; Welsh, Kevin M.; West, Robert.; Michl, Josef.
- Book ID
- 126811103
- Publisher
- American Chemical Society
- Year
- 1989
- Tongue
- English
- Weight
- 373 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0276-7333
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## Abstract The UV photolysis of [2.2]paracyclophanโene (3) and benzoโ[2.2]paracyclophanโene (4), matrixโisolated in argon at 10 K, results in the cleavage of the ethano bridge and formation of compounds 5 and 8, respectively. The IR and UV/Vis spectra are compared with __p__โxylylene and the benzy
Tetrafluoro-p-xylylene (3) has been generated by flash by comparison of experimental and calculated IR spectra. The temperature-dependence of the thermal fragmentation vacuum pyrolysis of octafluoro[2.2]paracyclophane (2) and subsequent trapping of the products in solid argon at 9 K. of paracyclop