Photochemistry of 1-allyl-4-aryltetrazolones in solution; structural effects on photoproduct selectivity
β Scribed by Ismael, Amin ;Serpa, Carlos ;Cristiano, M. Lurdes S.
- Book ID
- 120349183
- Publisher
- Royal Society of Chemistry
- Year
- 2013
- Tongue
- English
- Weight
- 982 KB
- Volume
- 12
- Category
- Article
- ISSN
- 1474-905X
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the chemistry of biradicals obtained by a-cleavage of B,y-unsaturated ketones, we elected to examine the photochemistry of three compounds (l-3) which on a-cleavage could yield the same biradical. Fischer and Zeeh'l had examined the photochemistry of the A-homocholestenone 1 and reported that on dir
Irradiation of 2,4-cyclohexadienones (L) usually produces ketenes. Most commonly, these ketenes either thermally recyclize to dienone or, in the presence of nucleophiles, react to form open-chain unsaturated acids or their derivatives.lm4 In special cases, however, the ketene may thermally cyclize t