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Photochemistry in the electronic ground state. Quantitative electrocyclic isomerization induced by multiphoton absorption of infrared laser radiation

✍ Scribed by Amnon Yogev; Ruth M.J. Benmair


Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
393 KB
Volume
46
Category
Article
ISSN
0009-2614

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✦ Synopsis


The efectrocyclic isomcrization of hexafluorocyclobutene (HFCB) induced by transversely excited infrared laser radiation was studied. A quantitative conversion of HFCB to the less thermodynamically stable hexafluorobutadien UiFB) was achieved in the presence of excess helium gas. The ti?velength and light intensity dependence were studied.