## Abstract On UV.‐irradiation in __i__‐octane the α,β‐unsaturated ketone **14** is transformed into a mixture of **15** and **16**.
Photochemische Reaktionen. 24. Mitteilung. Die UV.-Bestrahlung von Testosteron und 3-Oxo-17β-acetoxy-Δ1;5-androstadien. (Vorläufige Mitteilung)
✍ Scribed by B. Nann; D. Gravel; R. Schorta; H. Wehrli; K. Schaffner; O. Jeger
- Publisher
- John Wiley and Sons
- Year
- 1963
- Tongue
- German
- Weight
- 591 KB
- Volume
- 46
- Category
- Article
- ISSN
- 0018-019X
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✦ Synopsis
Abstract
- The photochemical reactivity of testosterone (1) is strongly influenced by the nature of the solvent. Dimerization (→18), pinacone formation (→19)), reactions between the steroid and the solvent molecules (→20a, 20b, 21) and stereospecific isomerizations (→2, 4) are observed.
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