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Photochemically Activated Cyclopropane Produced from the Photolysis of 1-Pyrazoline

โœ Scribed by Cadman, P.; Meunier, H. M.; Trotman-Dickenson, A. F.


Book ID
127233272
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
583 KB
Volume
91
Category
Article
ISSN
0002-7863

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In the course of our investigations on the photochemistry of a-chloroketones we have photolyzed exo-3-chlorobicyclo[2.2.l~hept-5-en-2-one (1). -Ketone L when photolyzed in methanol (0.05 l4, 1> through a Pyrex filter with Rayonet 3000 1 lamps results in the stereospecific formation of endo-6-carbome