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Photochemical transformations. XXX. Photochemical addition of 4,4-dimethyl-2-cyclohexenone to tetramethylethylene

✍ Scribed by Nelson, Peter J.; Ostrem, Dennis; Lassila, Jean D.; Chapman, Orville L.

Book ID
127008666
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
367 KB
Volume
34
Category
Article
ISSN
0022-3263

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## Abstract The photochemical behaviour of 2‐Bromo‐4,4‐dimethyl‐2‐cyclohexenone (1) was studied in 2‐propanol and cyclohexane. In both solvents (n‐π\*)‐excitation followed by intersystem crossing leads to population of a low‐lying triplet (T~1~) state, which can be quenched by 1,3‐cyclohexadiene bu