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Photochemical transformation of 6-chlorouracil and some alkylated analogues

✍ Scribed by Z. Kazimierczuk; D. Shugar

Book ID
115744631
Publisher
Elsevier Science
Year
1971
Weight
583 KB
Volume
254
Category
Article
ISSN
0005-2787

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transformed into 7 by a stereoselective intramolecular [2+2] cycloaddition reaction involving its furanic 13(16)-double Some neoclerodane (2-4) and labdane (5 and 6) diterpene ketones having a β-or γ-hydroxy function, an α-epoxy group, bond. Finally, the α-epoxy ketone 6 was rearranged to the 10(9Ǟ8