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Photochemical synthesis of phenanthrenes. Synthesis of aristolochic acid

✍ Scribed by S. Morris Kupchan; Henry C. Wormser

Publisher: Elsevier Science
Year: 1965
Tongue: French
Weight: 208 KB
Volume: 6
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)89960-8

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✦ Synopsis

A new general synthesis of substituted phenanthrene derivatives, involving photocyclization of substituted 2-iodostilbenes, is presented herewith. The usefulness of the method for the synthesis of nitrophenanthrenes, not readily accessible by other approaches, is illustrated in an efficient synthesis of the naturally-occurring tumor inhibitor, aristolochic acid

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