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Photochemical Synthesis of Octahydro- and 3a,4,5,6,7,7a-Hexahydro-benzo[b]thiophenes from Methyl (E)-4-Mercapto-2,6-heptadienoate and Alkenes or Alkynes via Consecutive Radical Ring Closure. Preliminary Communication

✍ Scribed by René Kiesewetter; Paul Margaretha


Publisher
John Wiley and Sons
Year
1987
Tongue
German
Weight
208 KB
Volume
70
Category
Article
ISSN
0018-019X

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✦ Synopsis


The yields indicated were determined by GC analysis and, therefore, reflect ratios of products only.

'H-NMR from 1 :1 mixture of 10 and 9. Configuration at C(5) unknown. 'H-NMR from 3:l mixture of 14 and 13. Configuration at C(2) unknown