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Photochemical synthesis of isoindolo[1,2-b] [3]benzazepine derivatives. Preparation of schőpf-schweickert amine VI

✍ Scribed by Heinz O. Bernhard; Victor Snieckus


Book ID
104248438
Publisher
Elsevier Science
Year
1971
Tongue
French
Weight
225 KB
Volume
12
Category
Article
ISSN
0040-4039

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✦ Synopsis


In 1965, outstanding efforts by ?5anta$ and coworkers culminated in the structural elucidation of rhoeadine (la) which proved to be the first member of the significant and biosynthetically intriguing 3 Rhoeadine group of alkaloids belonging to the benzylisoquinoline 4 family . Until recently, the state of the synthetic art in this area appeared to lie in dormancy. In view of the abrupt awakening of interest 5,6,7 , we wish to report our different approach 8 to this group of alkaloids which involves a new and apparently general type of


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Synthesis of 2-Substituted-1H-pyrrolo[2,
✍ Eric Desarbre; Sandrine Coudret; Cécile Meheust; Jean-Yves Mérour 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 655 KB

pyridines have been prepared from 7-azaindole by lithiation followed by addition of various electrophiles. A 7-azaolivacine analogue and a pyrido[3'2':4,5]pyrrolo[ 1,2-c]pyrido [3,2-d]pyrimidine have also been prepared.