Photochemical syntheses of 1,5- and 1,3-cyclooctadiene-iron carbonyls.

✍ Scribed by Ernst Koerner von Gustorf; Joseph C. Hogan

• Book ID: 104222712
• Publisher: Elsevier Science
• Year: 1968
• Tongue: French
• Weight: 213 KB
• Volume: 9
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(00)89521-0

✦ Synopsis

1,5_Cyclooctadiene-iron tricarbonyl (I) has been reported as a liquid (ni 1.5765) produced photochemically') or thermally') from Fe(C0)5 and 1,5-cyclooctadiene (II), and as an unstable solid melting just below room temperature obtained from refluxing II with Fe3(CO)i2 in bensene3). I has also been described in a footnote 4) as yellow crystals, m.p. 61-63'C. prepared from II F. r.<. Fe2 (CO)g. Recently the Mijssbauer parameters of I have been reported 5) without any tic III data on its preparation.