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Photochemical study of peroxy radical interactions in hydrocarbon oxidation

✍ Scribed by Tamás Vidóczy; Roger Lampert; Julia Lukács; Gábor Vasvári; Ágnes Keszler; Dezsö Gál


Publisher
Elsevier Science
Year
1981
Weight
139 KB
Volume
17
Category
Article
ISSN
0047-2670

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The rate coefficient for an alkyl peroxy (RO2)-~ alkyl hydroperoxy radical isomerisation reaction has been measured directly for the first time (with R = neo-pentyl). The alkyl radical was generated by the 248 nm pulsed photolysis of neo-pentyl iodide and the OH product of the peroxy radical reactio