Photochemical separation of metals in aqueous solution
β Scribed by Terence Donohue
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- English
- Weight
- 267 KB
- Volume
- 48
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
β¦ Synopsis
Several d-block transition elements have been separated from mixtures by photochemical means, using lines from various lasers. The species involved, oxalato complexes of Fe and Co, eshibit selective photoreduction following absorption in bands in the visible and near ultraviolet regions of the spectrum. This experiment is apparently the fmt demonstration of selective laser photochemistry in liquid phase mixtures of chemically related elements.
π SIMILAR VOLUMES
Photochemical degradation of benzotriazole is investigated in aqueous solution at 25Β‘C and pH values varying in the range 3Γ11. The quantum yields at di β erent pH values are evaluated by analysing the kinetics of the reacting system. Reaction kinetics are markedly a β ected by pH because of its inΓue
The oxidation of organic compounds on noble metal electrodes inaqueous solution is acompLex reaction due to the occurrence of several adsorbed intermediates and reaction products or by-products. This leads to a lot of electrocatalytic problems, such as the elucidation of the nature of the reaction p
The photochemistry of aqueous solutrons of iodide and bromide is investigated in the presence of high concentrations (2 x 10m2 M < C c 1.2 M) of nitrous oxide. In the iodide system, the photo-oxidation yfeids depend markedly on [N20]. The effect is attributed to the scavenging of solvated electrons