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Photochemical rearrangement of 2-nitrophenyl phenyl sulfoxide to 2-nitrosophenyl phenyl sulfone

โœ Scribed by Rikuhei Tanikaga; Yasuhiko Higashio; Aritsune Kaji

Book ID
108385046
Publisher
Elsevier Science
Year
1970
Tongue
French
Weight
181 KB
Volume
11
Category
Article
ISSN
0040-4039

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We have recently reported that treatment of the C3(-hydroxyaldehyde dlphenylmercaptals (I) with methyl-or n-butyllithlum leads to the formation of the corresponding phenylthlomethyl ketone In high yield.' This reaction Is considered to proceed through an Initial formation of the dlllthlated lntermed