Photochemical Reactivity of Azides
โ Scribed by Goetz Bucher
- Publisher
- John Wiley and Sons
- Year
- 2004
- Weight
- 47 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0931-7597
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๐ SIMILAR VOLUMES
Trimethylsilyl azide adds to the carbonyl carbon in a cage-opened fullerene derivative to form the first fullerenyl azide compound. The fullerene-bound azido group exhibits some unusual reactivity compared with that exhibited by other organic azido compounds. Heating the azidofullerene at 100 ยฐC onl
Photochemical rearrangements of 2,5-cyclohexadienones 7a and 7b to bridged --llb via zwitterions 10a and lob are described. ----Photorearrangements of 2,5-cyclohexadienones, L, generally occur from triazenes lla and the n + V\* excited triplet state.' Reorganization of electrons gives zwitterion 2,