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Photochemical reactions of [(η5-C5H5)Mn(CO)3] with Ph2P(S)(CH2)nP(S)Ph2[n=1, dppm(S)2; 2, dppe(S)2; 3, dppp(S)2]

✍ Scribed by Elif Subasi; Ozan S. Senturk; Fadime Ugur

Book ID
106546870
Publisher
Springer
Year
2004
Tongue
English
Weight
96 KB
Volume
29
Category
Article
ISSN
0340-4285

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130°C fiihrt zu rBu&H-CH(SiMe,),, das ober fBu2SiBr-CH(SiMe3)2 (Umsetzung mit Br2 in CCI. bei Raumtcmperatur) und rBu2SiF-CH(SiMe3)2 (einw6chige Umsetzung mit KF in CsH6 bei Raumtcmperatur in Anwcsenhcit von [18]Kronc-6) in ~Bu~S~F-CL~(S~MC,)~ umgewanddt w i d (einwtichige Umsetzung mit LiMe in Tetr