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Photochemical reaction of .alpha.,.beta.-epoxy esters in protic solvent

✍ Scribed by Tokuda, Masao; Chung, V. V.; Suzuki, Akira; Itoh, Mitsuomi

Book ID
127269341
Publisher
American Chemical Society
Year
1975
Tongue
English
Weight
306 KB
Volume
40
Category
Article
ISSN
0022-3263

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✍ R. Noyori; M. KatΓ΄ πŸ“‚ Article πŸ“… 1968 πŸ› Elsevier Science 🌐 French βš– 164 KB

In our earlier work on the photochemistry of 2,6-cycloheptadienone (I), we had shown that the course of the reaction is markedly influenced by the nucleophilicity of the solvent .employed (1). Irradiation of I in methyl alcohol gives a monocyclic ether II as the major primary product. On the other h