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Photochemical oxidation and dimerization of alkylbenzenes. Selective reactions of the alkyl side groups

✍ Scribed by Mordechai Pasternak; Abraham Morduchowitz

Publisher: Elsevier Science
Year: 1983
Tongue: French
Weight: 244 KB
Volume: 24
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)88319-7

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✦ Synopsis

Irradiations of alkylbenzene compounds in an oxygen atmosphere result exclusivelv in oxidation reactions. while in a less oxidative environ-. ment dimerization processes predominate. Under all conditions studied, the reactions took place only at one benzyl position. Recently there has been an interest in photooxidation of alkylbenzene derivatives related to air pollution, whereby harmful oxidants are produced by nitrogen oxides and alkylbenzene compounds. 1 Similarly, some industrial research efforts have been directed towards the prevention of undesirable photooxidations by the development of new photostabilizers and antioxidants. 2

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