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Photochemical Isomerization Reactions of Cyanopyrroles: A Theoretical Study

โœ Scribed by Su, Ming-Der


Book ID
126984433
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
301 KB
Volume
110
Category
Article
ISSN
1089-5639

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Photochemical cis-trans isomerization of
โœ I. Baraldi; M.C. Bruni; F. Momicchioli; J. Langlet; J.P. Malrieu ๐Ÿ“‚ Article ๐Ÿ“… 1977 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 750 KB

The cis-trans photoisomerization pathway of the s-trans-1,3-pentadiene is investigated on the basis of excited state potential curves calculated using the CIPSI method in the excitonic (PCILO type) scheme. It is shown that both direct and sensitized excitation of either isomer are followed by equipr