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Photochemical hydroxylation of 7,8-dimethylalloxazine (lumichrome). Structure elucidation of the irradiation product

✍ Scribed by B. te Nijenhuis; Miss A. C. Mulder; W. Berends

Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
391 KB
Volume
99
Category
Article
ISSN
0165-0513

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✦ Synopsis

Abstract

The synthesis of 8‐methoxy‐3‐(methoxycarbonyl)‐6,7‐dimethyl‐2‐(methylamino)quinoxaline is described. The synthesized compound appeared to be identical with the product obtained by degradation of the irradiation product of lumichrome. From this the conclusion is drawn that the irradiation product of lumichrome in water is 9‐hydroxylumichrome.

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