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Photochemical hole burning of cationic porphin/saponite intercalation compounds

โœ Scribed by Kazuaki Sakoda; Kazuhiko Kominami

Book ID
103031551
Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
441 KB
Volume
216
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

Intercalation compounds were synthesized from porphin derivatives with cationic substituents and saponite, which is a polycrystalline layered silicate. The formation of the intercalation compounds was confirmed by X-ray diffractions and elemental analysis. We found that the porphin molecules lay their planar skeleton parallel to the silicate layer. Besides, photochemical holes can be burned at least up to 50 K and the amount of spectral diffusion is smaller in these compounds than in a typical neutral porphin/polymer system.

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