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Photochemical generation of alkyl radicals and their reactions with methyl viologen radical cation and with transition-metal complexes in aqueous solution

✍ Scribed by Bakac, Andreja; Espenson, James H.


Book ID
126180761
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
573 KB
Volume
28
Category
Article
ISSN
0020-1669

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## Abstract In the reactions of Grignard reagents and __n__‐butyllithium the presence of transition metals and complexing solvents facilitates the formation of anion radicals. High radical concentrations, observable for some days at laboratory temperature, and very well resolved e.s.r. spectra of t