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Photochemical generation of aliphatic radicals from benzophenone oxime esters: simple synthesis of alkylbenzenes and alkylpyridines

✍ Scribed by Masato Hasebe; Takashi Tsuchiya


Book ID
104218844
Publisher
Elsevier Science
Year
1986
Tongue
French
Weight
209 KB
Volume
27
Category
Article
ISSN
0040-4039

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✦ Synopsis


Photolysis of benzophenone oxime esters, prepared with aliphatic carboxylic acids and benzophenone oxime, in benzene and pyridine generates various primary, secondary and tertiary aliphatic radicals selectively, and corresponding alkylbenzenes and alkylpyridines are produced in good yields, respectively.