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Photochemical Generation and Reactivity of the 5,6-Dihydrouridin-6-yl Radical

✍ Scribed by Newman, Cory A.; Resendiz, Marino J. E.; Sczepanski, Jonathan T.; Greenberg, Marc M.

Book ID
127326299
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
901 KB
Volume
74
Category
Article
ISSN
0022-3263

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ESR. and, in part, ENDOR. studies are reported on the radical anions of 5,5'and 6,6'-biazulenyl (1 and 2, resp.), as well as on their 1,1',3,3'-tetradeuterioderivatives (1-d4 and 2-d4). The reduction processes of 1 and 2 leading to these radical anions (1Q and 28) and the dianions (1" and 2e) have b