✦ LIBER ✦
Photochemical Generation and [4+2]-Cycloaddition of Singlet Oxygen in a Falling-Film Micro Reactor
✍ Scribed by K. Jähnisch; U. Dingerdissen
- Publisher
- John Wiley and Sons
- Year
- 2005
- Tongue
- English
- Weight
- 135 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0930-7516
No coin nor oath required. For personal study only.
✦ Synopsis
The presented falling‐film microreactor is suited for the generation and reaction of singlet oxygen for the photo‐oxygenation of olefins and allows for the first time conversions on a preparative scale. Due to the short holdup the concentration of the explosive endoperoxide is low in the whole reactor system and the endoperoxide is reduced to the final product immediately after leaving the reactor. The results show the feasibility of this reaction although the process is not yet optimized.