✦ LIBER ✦

Photochemical formation of CH3HgH in Hg/CH4/Ar matrices studied by FTIR spectroscopy

✍ Scribed by N. Legay-Sommaire; F. Legay

Publisher: Elsevier Science
Year: 1994
Tongue: English
Weight: 316 KB
Volume: 217
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(93)e1367-p

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✦ Synopsis

Mixed matrices of methane or deuterated methane and argon doped with mercury have been irradiated with a KrF laser at 249 nm. Methylmercury hydride is formed by reaction of Hg excited to the "PI state with CH4 or CD.,. The reaction products were identified by Fourier transform infrared spectrometry.

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