✦ LIBER ✦
Photochemical enrichment of diacetyl [15-3H] gibberellin-A3-7-aldehydes by a tritium isotope effect
✍ Scribed by M. Lischewski; H.-W. Liebisch; G. Adam
- Publisher
- John Wiley and Sons
- Year
- 1983
- Tongue
- French
- Weight
- 153 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0022-2135
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✦ Synopsis
of Sciences of the GDR, 2DR-4010 Halle (Saale), G e r m a n Democratic Republic During photocyclisation of 1 TO!and 155-tritiated diacetylgibberellin-A3-7-aldehydes to the cyclobutanols we found
an enrichment of the tritium labelled starting aldehydes by an isotope effect. The mechanism of the sterically controlled abstraction of the 15d-hydrogen/tritium-atom is discussed.