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Photochemical Electron Transfer Reactions of Tirapazamine

โœ Scribed by James S. Poole; Christopher M. Hadad; Matthew S. Platz; Zachary P. Fredin; Laura Pickard; Elisa Levya Guerrero; Margarita Kessler; Goutam Chowdhury; Delshanee Kotandeniya; Kent S. Gates

Book ID
111836830
Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
153 KB
Volume
75
Category
Article
ISSN
0031-8655

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โœ Eric W. Bischof; Jochen Mattay ๐Ÿ“‚ Article ๐Ÿ“… 1990 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 247 KB

Irradiating cyclohexenones containing an olefinic side chain under electron transferconditions (PET) leads to new spirocyclic products 3, as well as [2+2]-cycloaddition products 2. A new reductive cyclobutane ring opening allows photochemical conversion of cyclobutanes 2 to spirocyclic compounds 3.