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Photochemical decarbonylation of Mn2(μ-PPh2)2(CO)8 to form Mn2 (μ-PPh2)2(μ-CO)(CO)6 with a semi-bridging carbonyl

✍ Scribed by Takashi Kawamura; Takayoshi Sowa; Teijiro Yonezawa; Tokio Yamabe; Hideki Masuda; Tooru Taga; Katsunosuke Machida


Book ID
103223295
Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
201 KB
Volume
276
Category
Article
ISSN
0022-328X

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Synthesis, Structure, and Reactivity of
✍ Dr. Francisco J. García Alonso; Dr. Manuel García Sanz; Prof. Victor Riera; Dr. 📂 Article 📅 1988 🏛 John Wiley and Sons 🌐 English ⚖ 237 KB 👁 1 views

H,-elimination from 3 must also occur [Eq. (e)]."ll Note that this equilibrium involves the same 16-electron species implicated in Equation (c). The product-forming hydrido-ethyl (A) and hydridoethyl ethylene (B) species (Scheme 1) "downstream" of reaction (d) have not been observed under a variety