Photochemical de-t-butylation of 3,5-di-t-butyl-4-hydroxyphenyl ketones
✍ Scribed by Teruo Matsuura; Yoshihiko Kitaura
- Publisher
- Elsevier Science
- Year
- 1967
- Tongue
- French
- Weight
- 109 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
BeoentlP studies oonoeml6g the photoohemioal reaotivity of arontlo-ketone6 a6d their ring 6tabutitut6d
derivatives hate dram muoh attention.* Porter and suppan repotted that the photoohemioal dl6appearanoo of @ydroxybenrophenone is very 106 ($ -0.02) in iuopro@
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## Abstract Die Aminosäuren 3,5‐Di‐__tert__‐butyltyrosin (**1a**) und (3,5‐Di‐__tert__‐butyl‐4‐hydroxyphenyl)glycin (**2a**) werden synthetisiert. Beide Aminosäuren dürften für die Spin‐Markierung von Peptiden geeignet sein.
## HiOTCXHEMISTRY OF lM-r-NTYL KETONE Sl'UDIED BY MMR SPECTROSCOPY we wish to report tie resrrfts of an NMR study of the detailed mechanism of the photofysis of di-t-butyl ketone in perfluoramethyfcyclohexane at room temperature using radiation with wave~en~ greater than 3CKl m. During the photoly