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Photochemical cycloaddition of N-methyltriazolinedione to naphthalene

✍ Scribed by Kjell, Douglas P.; Sheridan, Robert S.

Book ID
120302190
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
430 KB
Volume
106
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES

Photochemical Diels-Alder addition of N-
Photochemical Diels-Alder addition of N-methyltriazolinedione to phenanthrene
✍ Steven J. Hamrock; Robert S. Sheridan πŸ“‚ Article πŸ“… 1988 πŸ› Elsevier Science 🌐 French βš– 247 KB

Visible irradiation of solutions of N-methyltriazolinedione and phenanthrene results in several Diels-Alder type adducts. The mechanism for these photoadditions is discussed.

ADDITION OF N-METHYLTRIAZOLINEDIONE TO B
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The addition of N-methyltriazolinedione (M) to biadamantylidene (A) gives the [2 + 2) adduct P, but clearly does not proceed in one step beause an aminoaziridinium intermediate (I) can be observed to build up during the reaction. The overall rate of P formation correlates with the amount of I that b