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Photochemical Carbonylation of Ethane under Supercritical Conditions

โœ Scribed by Thomas E. Bitterwolf; Dinara Lukmanova Kline; John C. Linehan; Clement R. Yonker; R. Shane Addleman


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
72 KB
Volume
113
Category
Article
ISSN
0044-8249

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Photochemical Carbonylation of Ethane un
โœ Thomas E. Bitterwolf; Dinara Lukmanova Kline; John C. Linehan; Clement R. Yonker ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 72 KB

Feasible photocatalysis: The rhodium catalyst [Rh(CO)(PMe ) Cl] photochemically transforms ethane to propionaldehyde in single-phase mixtures of ethane and in carbon dioxide/ethane single phases [Eq. (1)]. A side reaction of carbon dioxide with the catalyst to give OPMe and [Rh(CO) (PMe )Cl] or [Rh