Photochemical Carbonylation of Ethane un
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Thomas E. Bitterwolf; Dinara Lukmanova Kline; John C. Linehan; Clement R. Yonker
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Article
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2001
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John Wiley and Sons
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English
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Feasible photocatalysis: The rhodium catalyst [Rh(CO)(PMe ) Cl] photochemically transforms ethane to propionaldehyde in single-phase mixtures of ethane and in carbon dioxide/ethane single phases [Eq. (1)]. A side reaction of carbon dioxide with the catalyst to give OPMe and [Rh(CO) (PMe )Cl] or [Rh