The photolysis of 1-aryloxy-2-azidoanthraquinones (3) in benzene is described herein which gave 1-hydroxy-2-arylaminoanthraquinones (4) and two types of 5H-naphtho[2,3-c]phenoxazine-8,13-diones (5 and 6). Thermolysis of 3 yielded only one of phenoxazines 5 and small amount of 4. On the other hand th
โฆ LIBER โฆ
Photochemical and thermal transformations of diazo derivatives of 1-aryloxy- and 1-arylthio-2-aminoanthraquinones
โ Scribed by L. S. Klimenko; I. Ya. Mainagashev; E. P. Fokin
- Book ID
- 112423746
- Publisher
- Springer
- Year
- 1992
- Tongue
- English
- Weight
- 339 KB
- Volume
- 41
- Category
- Article
- ISSN
- 1573-9171
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Thermally, dithiines may react as dienophiles in [ 2 + 4] -cycloadditions. Photochemically, they afford [ 2+ 2 ] -cyclodimerization products in the absence of oxygen ; in its presence, they are degraded to CO2 and H2S among other photooxidation products. CT-complexes occur with tetracyanoethylene, m