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Photochemical and thermal reactions of thiones with substituted alkynes

✍ Scribed by Hans Gotthardt; Sonja Nieberl


Book ID
104212949
Publisher
Elsevier Science
Year
1976
Tongue
French
Weight
216 KB
Volume
17
Category
Article
ISSN
0040-4039

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Intramolecular photochemical and thermal
✍ Albert Padwa; Joel Smolanoff; Alan Tremper πŸ“‚ Article πŸ“… 1974 πŸ› Elsevier Science 🌐 French βš– 187 KB

Several in-depth studies from these laboratories have demonstrated that arylazirines undergo photocycloaddition with electron deficient olefins. 1-3 It has been suggested that these reactions proceed by way of irreversible opening of the three-membered ring to form a nitrile ylide intermediate which