Photochemical and thermal isomerization in polymer matrices: Azo compounds in polystyrene
β Scribed by Priest, W. J. ;Sifain, M. M.
- Book ID
- 104536169
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1971
- Tongue
- English
- Weight
- 377 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0449-296X
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π SIMILAR VOLUMES
## Ab initio calculations in a variation-perturbation scheme have been carried out on the three molecules of diazene, phenyldiazene and azobenzene with a view to clarifying the Z/E isomerization mechanism. It is found that, contrary to the usual belief, the rotational isomerization mechanism shows
The thermal cis-trans isomerization of azo dyes XC6H4N=NC6H4N(C2H5)2 (where X is H, OCH3, CN, and NOz) in poly(ethy1ene terephthalate) matrices, below the glass transition temperature, and in dibutylphthalate solutions has been studied kinetically in the temperature range 20-60Β°C. Kinetic behavior i