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Photochemical and Free Radical Decompositions of Oxetane 1

โœ Scribed by Margerum, J. D.; Pitts, J. N.; Rutgers, J. G.; Searles, S.


Book ID
125537799
Publisher
American Chemical Society
Year
1959
Tongue
English
Weight
770 KB
Volume
81
Category
Article
ISSN
0002-7863

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In contrast to simple imidazoles, l-methyl-2,4,5\_triphenylimidazole (1) produced stable oxetane photoadducts 3\_b -2 with good efficiency upon irradiation in the presence of benzophenone derivatives 2\_b -2 in acetonitrile solution. Irradiation in the solid-phase was also studied. The oxetanes 2 -Q