A 4 K matrix ESR study of the rearrangem
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Hachizo Muto; Kazumi Toriyama; Keichi Nunome; Machio Iwasaki
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Article
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1984
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Elsevier Science
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English
โ 376 KB
A 4 K matrix ESR study shows that the molecular radrcal cations of isopropyl formate and acetate, produced radio-IyticaJly in halocarbon matrices at 4-2 I(, undergo spontaneous rearrangement due to a selective intramolecular hydrogen shift from the tertiary C-H bond in the isopropyl group to the car