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Photochemical and ESR spectral evidence for a stereoselective rearrangement of radical cations derived from azoalkanes and bicyclopentanes

โœ Scribed by Adam, Waldemar; Walter, Herbert; Chen, Guo Fei; Williams, Ffrancon


Book ID
121263738
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
1009 KB
Volume
114
Category
Article
ISSN
0002-7863

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A 4 K matrix ESR study of the rearrangem
โœ Hachizo Muto; Kazumi Toriyama; Keichi Nunome; Machio Iwasaki ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 376 KB

A 4 K matrix ESR study shows that the molecular radrcal cations of isopropyl formate and acetate, produced radio-IyticaJly in halocarbon matrices at 4-2 I(, undergo spontaneous rearrangement due to a selective intramolecular hydrogen shift from the tertiary C-H bond in the isopropyl group to the car