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Photochemical [2+2] dimerization of [6](1,4)-anthracenophane

โœ Scribed by Tobe, Yoshito; Takahashi, Tohru; Kobiro, Kazuya; Kakiuchi, Kiyomi


Book ID
121448454
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
565 KB
Volume
113
Category
Article
ISSN
0002-7863

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Photochemical dimerization of 2,4-cycloo
โœ G.L. Lange; E. Neidert ๐Ÿ“‚ Article ๐Ÿ“… 1971 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 203 KB

Cantrell recently reported' that U.V. irradiation 2,4-cyclooctadienone (1) in methanol or ether gave in low yield (6-10%) a dimer, m.p. 173-174'. The proposed head-to-head cin-atiti structure (as in 4) was based on spectral data, recovery of starting dimer after treatment with methanolic sodium meth