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Photocatalytic Ring Opening of α-Epoxyketones: 1,3-Dioxolane Formation.

✍ Scribed by Hamid R. Memarian; Farzad Nikpour


Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
33
Category
Article
ISSN
0931-7597

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Cationic ring-opening polymerization of
✍ Jaekyeung Park; Nobuhiro Kihara; Takeshi Endo 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 269 KB

## Abstract 2‐Isopropenyl‐4‐methylene‐1,3‐dioxolane (1) undergoes cationic polymerization in donative solvents without crosslinking to afford poly(ether‐ketone) 2 having two unitstructures. When solvents having medium donor number (DN = 14,1–17,1), such as acetonitrile, dioxane, ethyl acetate, and