## Abstract A new photocatalyst, named TiO~2~ microspheres, prepared by a solโsprayingโcalcination method, can freely suspend with air bubbling in its aqueous suspension and easily settle down from a water phase under gravity. The experimental results demonstrated that TiO~2~ microspheres had bette
โฆ LIBER โฆ
Photocatalytic degradation of methylbutandioic acid (MBA) in aqueous TiO2 suspension: influences of MBA adsorption on the solid semi-conductor
โ Scribed by Didier Robert; Jean Victor Weber
- Book ID
- 104362768
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- English
- Weight
- 126 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0959-6526
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โฆ Synopsis
In the present work we describe the photocatalytic degradation of methylbutandioic acid (MBA), focusing particularly on adsorption of the MBA on TiO 2 surface. We observe a very fast surface carboxylate formation, a decrease of the surface carboxylates during the reaction and an apparent zero order kinetic for the degradation of MBA. We conclude that the main way of MBA degradation is its reaction in the solution, and not on the surface of TiO 2 . The influence of the surface carboxylates on the efficiency of the catalyser is under study.
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