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Photocatalysis IV. Preparation and characterization of a stable copper(I) triflate·trans-cycloheptene complex

✍ Scribed by J. Th. M. Evers; A. Mackor

Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
102 KB
Volume
98
Category
Article
ISSN
0165-0513

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Upon irradiation by 254 nm light of a mixture of cyclohexene and cycloheptene in the presence of copper(I) triflate (= trifluoromethanesulfonate), a very selective co-dimerisation takes place to give trans-transoid-trans-tricyclo[7.4.0.02'8~tridecane. / The photochemical cyclodimerization of cycloal