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Photobehaviour of phenyl-containing methacrylate polymers—II: Dependence upon the number of chromophores in the structural unit

✍ Scribed by E.B. Abuín; E.A. Lissi; L. Gargallo; D. Radic


Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
256 KB
Volume
16
Category
Article
ISSN
0014-3057

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✦ Synopsis


Emission spectra and photobehaviour were investigated for polymers and copolymers derived from poly(methyl methacrylate) with one to three phenyl groups for each monomer molecule. The results show that excimer emission increases with the number of phenyl groups for the structural unit and with the temperature, and that it decreases when the thermodynamic character of the solvent improves. The results are interpreted in terms of excimer formation between non-nearest neighbours.