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Photo-oxygenation of tropone. A convenient synthesis of 5-hydroxytropolone and tropolone

✍ Scribed by Masaji Oda; Yoshio Kitahara


Book ID
104239739
Publisher
Elsevier Science
Year
1969
Tongue
French
Weight
87 KB
Volume
10
Category
Article
ISSN
0040-4039

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## Abstract Acid‐catalysed decomposition of tropyl ether gives tropone and cycloheptatriene in 83.5 and 90 % yields, respectively. Chlorination of tropone in carbon tetrachloride solution yields tropone dichloride, which can be made to isomerize to the hydrochloride of 2‐chlorotropone; 2‐chlorotro