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Photo-oxidation of α-phellandrene: The formation of cyclohexadienyl hydroperoxides and their reduction to arene 1,4-hydrates

✍ Scribed by Robert Atkins; Howard A.J. Carless

Book ID: 104228166
Publisher: Elsevier Science
Year: 1987
Tongue: French
Weight: 237 KB
Volume: 28
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)96872-2

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✦ Synopsis

Dye-sensitised photo-oxidation of cz-phellandrene (3) yields, besides the expected endoperoxides, the cyclohexadienyl hydroperoxides ( ) and ( ); reduction of these latter gives the unstable arene 1,4-hydrates ( ) and ( ).

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