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Photo-oxidation of Methyl Orange sensitised by zinc oxide. Part 1.?Mechanism

✍ Scribed by Darwent, James R.; Lepre, Anne


Book ID
120310423
Publisher
The Royal Society of Chemistry
Year
1986
Weight
823 KB
Volume
82
Category
Article
ISSN
0300-9238

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The stopped-flow measurements on the disappearance of alkaline osmium(VII1) at 402 nm indicated a first-order dependence each in [Os(VIII)] and [HCHO]. The pseudo first-order rate constant hobs ([HCHO] & [Os(VIII)]) decreased with increasing [OH-]. The ionic strength, however, had no effect on kobs.