Photo-oxidation of alkanes by metal oxide semiconductors
โ Scribed by C. Giannotti; S. Le Greneur; O. Watts
- Book ID
- 104226264
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- French
- Weight
- 132 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
โฆ Synopsis
The partial conversion of alkanes to the corresponding ketones has been achieved byirradiation of a suspension of semiconductor powder in oxygen-saturated alkanes. The reactivity of thermally and chemicallydoped semiconductor and the effect of chemisorbed water have also been studied.
๐ SIMILAR VOLUMES
Photo-oxidation of the metal carbyne complexes ($-C?'Hs)LILM=CR (M =Mo, W, L,, b=CO, P(OMej3; R=phenyl, cyclopropyl) generates radical cations that are extremely reactive. Depending on the reaction conditions, either the oxidized species exhibit the ligand exchange and atom abstraction processes typ