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Photo-induced cyclization of cis,cis-2,8-cyclononadienone via the cis,trans isomer

✍ Scribed by R. Noyori; Y. Ohnishi; M. Katô


Publisher
Elsevier Science
Year
1971
Tongue
French
Weight
181 KB
Volume
12
Category
Article
ISSN
0040-4039

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✦ Synopsis


The photochemistry of cross-conjugated cyclic dienones is markedly influenced by ring size. The well-known rearrangement of 2,5-cyclohexadienones (I)


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The photo-sensitized isomerization of ci
✍ H. Nozaki; Y. Nisikawa; Y. Kamatani; R. Noyori 📂 Article 📅 1965 🏛 Elsevier Science 🌐 French ⚖ 261 KB

Th8 cls-trans lsomerization of ois.trans.trans-l,r),+qclododecatrfene (I) by free radicals has r8centlY been described bv Duck and I&eke (1) to afford the all-trans triene.(II) in 45%